PG Group Top 10

the ten best molecules

The 10 best molecules selected for their originality, complexity and the impact of the work from the group’s perspective and is presented in the order of their priority.

No 1

Stacks Image 11
Demonstrated the potential of palladium N-heterocyclic carbene (NHC) complexes as pharmaceuticals for anticancer applications.
J. Am. Chem. Soc. 2007, 129, 15042-15053.

No 2

Stacks Image 23
Stronger Argentophilic interaction over Aurophilic interaction in a discrete pairwise model complex questioned the popular perception.
Inorg. Chem. 2008, 47, 230-240.

No 3

Stacks Image 35
The second example of amine-free Sonogashira reaction under ambient aqueous condition for this class of complexes.
Chem. Eur. J. 2008, 14, 6646-6655.

No 4

Stacks Image 47
Highly active catalyst for the Suzuki-Miyaura cross-coupling reaction.
Organometallics 2007, 26, 958-964.

No 5

Stacks Image 73
Highly active catalyst for the regioselective alkyne hydroamination reaction.
Inorg. Chem. 2010, 49, 4972-4983.

No 6

Stacks Image 75
High anticancer activity with significant selectivity towards the cancer cells over the normal ones.
ACS Omega, 2017, 2, 4632-4646

US Patent No.: US 10421769 (Granted on Sep 24, 2019)

Indian Patent No.: 380602 (Granted on Oct 28, 2021).

No 7

Stacks Image 87
The first example of a Hiyama coupling and also the first example of a tandem catalysis by any palladium acyclic diamino carbene (ADC) complex.
ACS Omega, 2018, 3, 1740-1756.

US Patent Application Serial No. 16/168,434.

No 8

Stacks Image 101
Efficient asymmetric bifunctional catalysis for the base-free Michael addition reaction under ambient conditions.
Eur. J. Inorg. Chem., 2015, 1604-1615.

No 9

Stacks Image 113
Structurally intriguing chiral oxazoline-fused imidazole derived N-heterocyclic carbene (NHC) catalysts prepared from readily available and cheap amino acids without any chiral resolution.
Eur. J. Inorg. Chem., 2017, 3253-3268.

No 10 (Joint)

Stacks Image 125
Efficient small molecule structural and functional mimics of Purple Acid Phosphatase (PAP) enzyme.
ACS Omega, 2017, 2, 4737-4750.
Stacks Image 135
The first iron catalyst of fused imidazo[1,5-a]pyridine derived N-heterocyclic carbene (NHC) ligands for the β-enaminone synthesis.
Eur. J. Inorg. Chem. 2019, 295-313.

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